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Chemistry (semester-5) 2017- previous question papers download in Telugu and English
Subject :-(chemistry)
Subject name :-(Chemistry)
Year :-(2017)
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Syllabus of chemistry -5
Addition of HX, Markonikov's rule addition of H20, HOX, H2SO4 with mechanism and addition of HBr in the presence of peroxide (anti-Markonikov's addition). Oxidation (cis- additions) - hydroxylation by KMnO4, OsO4, trans addition - peracids (via epoxidation), hydroboration, ozonolysis - location of the double bond. Dienes - Types of dienes, reactions of conjugated dienes - 1,2 and 1,4 addition of HBr to 1,3 - butadiene and Diels - Alder reaction. Physical properties: Acidity of terminal alkynes (formation of metal acetylides) preparation of higher alkynes, chemical reactivity - electrophilic addition of X2, HX, H20 (tautomerism), oxidation (formation ofenediol, 1,2 diones and carboxylic acids), and reduction (Metal - ammonia reduction, catalytic hydrogenation).
Alicyclic Hydrocarbons: Nomenclature, preparation by Freund's method, Dickmann, heating dicarboxylic metal salts. Proper- ties - reactivity of cyclopropane and cyclobutane by comparing with alkanes. Stability of cycloalkanes -Baeyer strain theory, Sachse and Mohr predictions, and Pitzer strain theory. Conformational structures of cyclopentane, cyclohexane.
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I have a lot of previous question papers for every semester ( KAKATIYA UNIVERSITY).
Here, you can download the all previous question papers of any semester for free.
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Click the link below to download the PDF file
Here, you can download the all previous question papers of any semester for free.
Chemistry (semester-5)
Chemistry (English medium) 2017 -question-paper download
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Chemistry (Telugu medium) 2017 -question-paper download
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Important questions
1. Explain the magnetic properties of transitional metals.
2. How composition of metal complexes is determined by Job's method?
3. Explain the applications of Ziegler-Natta catalyst in industry.
4. What is Hoffman bromamide reaction? Outline its mechanism.
5. Explain the acidic nature of Pyrrole and basic nature of Pyridine.
6. Explain Hinsberg method of separation of mixture of amines.
7. Explain about pseudo order reactions and parallel reactions.
8. Define rate of a reaction. Discuss the effect of catalyst on rate of a reaction.
9. A first order reaction is 50% completed in 20 minutes. Calculate the time required for 75% completion of the same reaction.
10. Explain the following with examples:
(i) Chromophore
(ii) Auxochrome
11. Explain different modes of vibrations of polyatomic molecules in IR Spectroscopy.
12. Explain Grotthus-Draper law and Stark-Einstein law of Photochemical equivalence.
13. (a) What are Labile and inert complexes.
(i) Explain with suitable examples.
(ii) Explain the crystal field splitting of d-orbitals in Tetrahedral complexes.
Or (b) (i) Explain the factors affecting the stability of metal complexes.
(ii) What is Chelate effect? Explain in detail. 14. (a) (i) What is Gabriel phthalimide synthesis? Write the method of preparation of ethylamine by this method.
(ii) How do you prepare furan and thiophene by Paul-Knorr synthesis?
Or
(b) (i) How Cyanides and Isocyanides are prepared from Alkyl Halides?
(ii) Compare the aromaticity and reactivity of Pyrrole, Furan and Thiophene.
15. (a) (i) Derive an equation for the rate constant of a second order reaction.
(ii) Explain the collision theory of reaction rates.
Or
(b) (i) Derive an equation for the rate constant of a first order reaction.
(ii) What is half life of a reaction? Half life of a first order reaction is 100 minutes. Calculate its rate constant.
16. (a) (i) Explain Bathochromic shift and Hypsochromic shift with suitable exam
(ii) What is quantum yield? Explain the reasons for high quantum yield of Photochemical reaction between H, and Cl, reacation.
Or
(b) (i) Write a short note on different types of molecular spectroscopy.
(ii) Explain the laws of photochemistry.
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